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Nanoscientists Describe Electron Movement through Molecules

Nanoscientists Describe Electron Movement through Molecules

September 30, 2005

Laptop Battery ATHENS, Ohio - Molecular electronics is the ultimate miniaturization of electronics. In this area of research, scientists have been studying the movement of electrons through individual molecules in an effort to understand how they might control and use the process in new technologies. Computers and thousands of other devices could become vastly faster, smaller and more reliable than conventional transistor-based (wire-based) electronics.

radical damage takes place on an atomic level. Molecules are made of atoms, and a single atom is made up of protons, neutrons, and electrons. Electrons are always found in pairs. However, when oxygen molecules are involved in a chemical reaction, they can lose one of their electrons. This oxygen molecule that now has only one electron is called a free radical. With only one electron the oxygen molecule must quickly find another electron, and it does this by taking the electron from another molecule. When that molecule in turn loses one of its electrons, it too must seek out another, in a continuing reaction. Molecules attempting to repair themselves in this way trigger a cascading event called " radical damage." radical damage takes place in a fraction of a second. Antioxidants are substances that prevent oxidative damage from being triggered. See antioxidant.

Thinkpad A team of Ohio University and Brazilian physicists has taken another step toward this goal. In the Rapid Communication section of the Sept. 15 issue of the journal Physical Review B, the researchers present a new theory of how electrons interact in a molecule.

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Microsoft In the new paper, the team describes what happens to electrons when scientists put two molecules between electrodes, which are bits of tiny conducting wire. Existing theoretical models of molecular electronics take into account that electrons avoid each other, according to Nancy Sandler, Ohio University assistant professor of physics and astronomy. The scientists report that molecular vibrations, in addition to strong electronic interactions, will produce unexpected "transport channels." The electrons move through the molecule while the molecule vibrates, said Sergio Ulloa, co-author of the paper and Ohio University professor of physics and astronomy.

generating process by acting as a shuttle to transport both electrons and protons from one bioenergy enzyme to another. Each CoQ molecule carries electrons and protons from donor enzymes to acceptor enzymes. They then return to pick up more electrons and protons. over again, thousands of times a second! Every electron and proton from which energy is to be extracted must first be transported to that appropriate enzyme by a molecule of Coenzyme Q10

Laptop Computers "The electrons go through the molecule like a pinball and they leave all the bells ringing (atoms moving) as they pass by," said Ulloa, adding that this model focuses on the general behavior of short molecules. Other scientists studying molecular electronics, he noted, are using longer molecules, such as DNA or carbon-based molecules, to serve as longer "wires" or connectors.

Three covalent bonds. Each of the three lines represents the shared pair of electrons in a covalent bond. Some textbooks omit the nonbonding electrons for simplicity. Because the hydrogen atom has its single 1 s orbital completed with only 2 electrons, the hydrogen chloride molecule is drawn as shown in Figure 7 . Figure 7 The hydrogen chloride molecule.

Laptop Computer The collaborators on this project - which included Ulloa, Sandler, Brazilian exchange student Edson Vernek and professor Enrique Anda of the Pontifícia Universidade Católica in Rio de Janeiro, Brazil - describe another fascinating capability of the electrons: "The electrons 'remember' not only where they are, but where they have been," Ulloa said. "When the oscillations of the molecules are 'just right,' the electrons are either pushed through more efficiently or trapped momentarily in the molecule - a phenomenon physicists call 'Rabi-assisted tunneling.' The electrons can really get trapped, like in the pinball machine."

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Desktop Computer This electron "trapping" could make molecular transmission even more efficient and help develop molecular switches and other applications.

Notebooks Molecular electronics is a booming field in physics right now. Scientists have been able to manipulate molecules for only last 15 years, Sandler said, and it may be at least another 20 years before consumers see molecular technology in commercially available devices.

Lenovo The research collaboration between Ohio University, the Pontifícia Universidade Católica in Rio de Janeiro, Brazil, and the Universidad de Buenos Aires, Argentina, is supported by the National Science Foundation through the project "Correlation Effects and Transport in Nanostructured Materials." The Brazilian Coordination of Improvement of the Personnel of Superior Level (CAPES) supported Vernek's visit to Ohio University.

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